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June 2004 Environmental Research Update



Welcome to the first issue of the Wisconsin Focus on Energy Environmental Research Update. This newsletter will be published periodically to feature progress on projects funded by the Focus on Energy Environmental Research Program, along with reports on the program's outreach activities. Please forward this newsletter to colleagues who may be interested in our program or research projects.

What is the Environmental Research Program? This program is part of the Wisconsin Focus on Energy public benefits program. Funding is set aside each year for research into the environmental effects of electrical generation and transmission in Wisconsin. Projects are chosen in a competitive RFP process.

The Environmental Research Program's primary goal is to identify and fill gaps in the body of existing knowledge about the environmental impact of the electricity industry. Another major goal is to find effective ways to communicate the results of this research to legislators and policy makers who will be formulating future regulations.

RESEARCH PROJECTS DUE TO BE COMPLETED IN 2004
In addition to the MTN and NDN Networks Monitoring Projects, and the University of Iowa study Quantifying Carbon Storage in Wisconsin Forests, the Environmental Research Program expects results from eight additional research projects by the end of 2004: State of the Science on the Ecological Effects of Transmission Line Siting and Construction
Project completion scheduled: June 2004
Principal Investigator: Susan Tikalsky, Resource Strategies, Inc.
Email: tikalsky@rs-inc.com

For over 50 years, there has been extensive research conducted on the effect of transmission lines on the ecology of the local environment. The purpose of this project is to synthesize existing work into a summary of what is and is not known, and to present that body of knowledge integrated with a critical analysis from interviews with scientists involved in current research. The outcome of this effort will be a comprehensive account of the "state of the science" on studies of ecosystem fragmentation and its effects on species diversity and invasive species in relation to transmission-line rights-of-way, particularly in the Midwest. The resulting information will be a critical resource for all parties involved with routing activities, and will help to reduce the confusion and difference of opinion over the state of knowledge as it exists today. Measuring Vertical Fluxes of Gaseous Elemental Mercury Near Several Major Sources in Wisconsin
Using Relaxed Eddy Accumulation
Project completion scheduled: December 2004
Principal Investigator: Mark K. Allen, Wisconsin Department of Natural Resources
Email: mark.allen@dnr.state.wi.us

The Wisconsin Department of Natural Resources is currently developing a rule to control mercury emissions released to the atmosphere from coal-fired electric utility plants and other major sources. To support evaluation of the rule, the Department is developing a modeling system for Wisconsin and the Great Lakes region. The vertical flux of mercury near land surfaces needs to be quantified to more accurately model the potential impact of mercury emissions to the state from coal-fired electric utility plants and other major sources. This project seeks to measure gaseous elemental mercury fluxes in the vicinity of coal-fired electric utility plants and other major sources using a conditional sampling method called Relaxed Eddy Accumulation. Projecting Impacts of Greenhouse Gases on Carbon Sequestration by Wisconsin Forests
Project completion scheduled: December 2004
Principal Investigator: Eric Kruger, Associate Professor, Department of Forest Ecology and Management, UW-Madison
Email: elkruger@facstaff.wisc.edu

Wisconsin's forests harbor the potential to sequester considerable amounts of the carbon emitted (as carbon dioxide) through fossil fuel combustion, thereby helping to mitigate the effects of these emissions on atmospheric chemistry and global climate. In turn, Wisconsin's forests are quite sensitive to levels of atmospheric carbon dioxide and other trace gases, such as ozone, which are increasing rapidly. The Aspen Free-Air CO2 and O3 Enrichment Study (Aspen FACE) is uniquely situated to study this complex topic in Wisconsin. In this project, we will utilize data from Aspen FACE, along with air quality data from the WDNR Air Management Program, to model and project impacts of elevated levels of CO2 and O3 on carbon sequestration by Wisconsin forests during the next century. Mercury in Power Plant Combustion By-Products
Project completion scheduled: December 2004
Principal Investigator: Ken Ladwig, Research Manager, Electric Power Research Institute, Palo Alto, California
Email: keladwig@epri.org

Mercury occurs in coal combustion by-products (CCBs) produced at power plants in concentrations typically ranging from about 0.05 mg/kg to 1.0 mg/kg. Concentrations in CCBs are expected to increase as a result of the federal and state initiatives to reduce mercury air emissions from power plants, resulting in greater capture in the fly ash. It is important to understand the fate of mercury captured in CCBs, so that appropriate management steps can be taken to ensure that new problems are not created by transferring the mercury from one media to another. This project will establish mercury concentrations in field leachates at CCB sites in Wisconsin, evaluate mercury leaching in the presence of ammonia from NOx control technologies, and develop laboratory data on volatilization of mercury from ash samples. Mercury Chemistry in Power Plant Plumes
Project completion scheduled: September 2004
Principal Investigator: Leonard Levin, Ph.D., Electric Power Research Institute, Palo Alto, California
Email: llevin@epri.com

Recent field and pilot-scale results indicate that divalent mercury emitted from power plants may rapidly transform to elemental mercury within the power plant plumes. To establish the presence, direction, and rate of these reactions, it is necessary to measure power plant plumes relatively close to the stack exit, and compare mercury composition there with measured composition within the stack. This project seeks to establish whether significant reduction or oxidation reactions occur to mercury emitted from coal-fired power plants, and what numerical redox reactions rate should apply to these reactions for extension to other sources and for modeling of power plant mercury plumes locally, regionally, and nationally. Comparative Toxicity of Secondary Coal Combustion and Mobile Source Emissions
Project completion scheduled: December 2004
Principal Investigator: Annette Rohr, Electric Power Research Institute
Email: arohr@epri.com

The promulgated National Ambient Air Quality Standard (NAAQS) for fine particulate matter (PM2.5) is mass-based, which assumes that all PM is equal with respect to health effects. However, since PM is derived from multiple sources and varies widely in composition, it is unlikely that all components are equally harmful to human health. This project investigates the role played by specific emissions sources and components in the induction of adverse health effects by examining the relative toxicity of coal combustion and mobile source (gasoline and/or diesel engine) emissions and their oxidative products. The study findings will help to answer questions regarding which constituents of PM are responsible for the negative health outcomes observed, the likely sources of these constituents, and the degree to which further regulation of PM will improve human health. Evaluation of Fin Clips as a Non-lethal Approach for Estimating Mercury Concentrations in Fish
Project completion scheduled: December 2004
Principal Investigator: Dr. Kristofer Rolfhus, River Studies Center, UW-La Crosse
Email: Rolfhus.kris@uwlax.edu

Existing approaches for monitoring mercury content in sport fishes involve the dissection of sampled fish and the subsequent analysis of axial muscle tissue or edible filets, a process requiring the removal of analyzed fish from the sampled population. Alternative approaches for non-lethal, non-invasive sampling for monitoring mercury in game fishes are desirable. This project examines whether analysis of methylmercury in a pelvic fin clip is a suitable substitute for the determination of total mercury content in filets. Linear regression will be used to determine the relation between concentrations of mercury in axial muscle and pelvic fins from fish within each lake studied. The slopes of the regression equations will be compared to determine if the relations are constant among lakes and to evaluate the utility of pelvic fins as a useful management tool in the determination of total mercury content in resident sport fish. OTHER CURRENT PROJECTS
Research projects scheduled for completion in 2005 and beyond include the following:

Lichen Bioaccumulation and Bioindicator Study near Alliant Energy Columbia Generating Facility
Project completion scheduled: March 2005
Principal Investigator: Susan Will-Wolf, Botany Department, UW-Madison

Impacts of Forest Management Activities on Carbon Sequestration and GHG Emissions
Project completion scheduled: June 2005
Principal Investigator: Stith T. Gower, Professor, Department of Forest Ecology and Management, UW-Madison

Fate andTransport of Mercury in a Recovering Watershed
Project completion scheduled: June 2005
Principal Investigator: James P. Hurley, Associate Scientist, Water Science and Engineering Laboratory, UW-Madison

Population-based Methylmercury Exposure Assessment
Project completion scheduled: June 2005
Principal Investigator: Lynda Knobeloch, Ph.D., Wisconsin Department of Health and Family Services

Assessing the Ecological Risk of Mercury Exposure to Common Loons
Project completion scheduled: June 2005
Project Manager: Michael W. Meyer, Wisconsin Department of Natural Resources, Bureau of Integrated Science Services, Rhinelander, WI
Study Director: Kevin P. Kenow, U.S. Geological Survey, Upper Midwest Environmental Science Center (UMESC), La Crosse, WI

Mercury in Selected Fish Species over Time
Project completion scheduled: December 2007
Principal Investigator: Candy Schrank, Fisheries Management and Habitat Protection, Wisconsin Department of Natural Resources

Changes in Biodiversity in Selected Natural Communities Related to Global Climate Change
Project completion scheduled: June 2008
Principal Investigator: Craig Anderson, Program Botanist, Natural Heritage Inventory Bureau of Endangered Resources, Wisconsin Department of Natural Resources PROJECTS IN FOCUS:

Project results from the University of Iowa: Quantifying Carbon Storage in Wisconsin Forests
Principal Investigator: Jerald Schnoor, Center for Global and Regional Environmental Research
Email: jerald-schnoor@uiowa.edu

Addressing climate change is a challenge that will call on many disciplines. The Center for Global and Regional Environmental Research (CGRER) at the University of Iowa has completed a project funded by the Environmental Research Program that adds an important tool to the battle against climate change. This project marries geographic information systems (GIS) technology with techniques from soil and forestry science to provide important information for climate policy.

CGRER has developed a method for quantifying the carbon stored in Wisconsin's 16 million acres of forested land. This method uses data collected by the USDA and the Wisconsin DNR to produce an estimate of carbon stored in forest soils and biomass. CGRER found that around 288 million metric tons of carbon are stored in Wisconsin forest soils, and that about 700,000 metric tons of carbon are taken up by these soils every year. Forest biomass - leaves and tree trunks - store about 350 million metric tons of carbon and add around 4 million metric tons to this total yearly. Combined, this equals about 13 percent of the greenhouse gas emitted by Wisconsin utilities each year.

Why does this matter? Strategies to address climate change will not only include techniques to reduce emissions of greenhouse gases but also those that increase the use of natural mechanisms to store carbon. The CGRER model helps to make better estimates of the role that forest management can play in reducing the effects of climate change. And, having developed and tested the model for Wisconsin, it can be rapidly and inexpensively adapted to other forest environments.

This model improves our ability to estimate the carbon storage capacity of forests, and will be of interest to anyone concerned with climate change or forestry management policy. WDNR Monitoring Wisconsin's piece of the puzzle: The National Atmospheric Deposition Program
Principal Investigator: Bruce Rodger, Air monitoring Field Operations Team Leader, WDNR
Email: rodgeb@dnr.state.wi.us

The Focus on Energy Environmental Research Program recognizes the vital importance of monitoring certain aspects of environmental quality, and particularly the need to collect data continually over time. Only then will we understand where pollution mitigation priorities lie, and whether strategies that have been implemented have been effective or not. Two ongoing projects funded by the Environmental Research Program not only monitor conditions in Wisconsin, but as part of two longstanding national networks, they assist in monitoring trends both regionally and nationwide.

Since 1980, the Wisconsin Department of Natural Resources (WDNR) has participated in the National Trends Network (NTN), which was established by the National Atmospheric Deposition Program (NADP) in 1978 to measure a variety of chemicals in the atmosphere. The NADP/NTN grew from 22 stations at the end of its first year, to over 240 sites spanning the continental United States, Alaska, Puerto Rico, and the Virgin Islands. WDNR presently operates a network of seven NTN stations throughout Wisconsin. (View national NADP/NTN sites at http://nadp.sws.uiuc.edu/sites/ntnmap.asp)

In 1995, NADP established a secondary network of deposition monitoring stations, the Mercury Deposition Network (MDN), for the specific purpose of measuring the deposition of mercury throughout North America. Wisconsin participated in the establishment of this network from its beginning. WDNR presently operates five MDN stations in Wisconsin. There are now over 77 active sites in the MDN network including stations across the U. S. and Canada. Stations for both networks collect samples of precipitation for analysis, and all samples are sent to one central laboratory to keep data precise and consistent. (See map at http://nadp.sws.uiuc.edu/mdn/sites.asp)

Historical levels of pollutants in the atmosphere provide important clues as to what is happening to the chemistry of Wisconsin's precipitation today. Long-term changes in the atmosphere occur very slowly, obscured by wide month-to-month variability in chemistry measurements. In order to see beyond the short-term changes, it is necessary to analyze precipitation samples collected by NTN and MDN sites over many years.

The National Trends Network (NTN)
Scientists and policy makers use the data provided by the NTN to examine the effectiveness of air quality regulations, determine whether changes in land use are affecting atmospheric conditions and answer other questions regarding atmospheric deposition. The precipitation at each NTN station is collected weekly according to strict clean-handling procedures. It is then sent to the Central Analytical Laboratory (Illinois State Water Survey at the Univ. of Illinois, Champaign, IL) where it is analyzed for hydrogen (acidity as pH), sulfate, nitrate, ammonium, chloride, and base cations (such as calcium, magnesium, potassium and sodium). Excellent quality assurance programs ensure that the data remain accurate and precise.

A continuous record of atmospheric deposition data for Wisconsin has been generated through Wisconsin's participation in the NADP/NTN network since 1980. Data from Wisconsin's NADP/NTN stations has established a database to measure trends in precipitation chemistry and deposition of the above constituents to precipitation across Wisconsin. This data is critical to determine the changes in atmospheric deposition in Wisconsin with time. Deposition trends will allow policymakers to determine if strategies developed to reduce harmful atmospheric deposition in Wisconsin are working.

The Mercury Deposition Network (MDN)
WDNR has kept ongoing records of mercury deposition data for Wisconsin since it began participating in the MDN network in 1995. The objective of the MDN is to develop a national database of weekly concentrations of total mercury in precipitation and the seasonal and annual flux of total mercury in wet deposition. The MDN data will enable researchers to determine seasonal and annual fluxes of mercury in precipitation falling on lakes, wetlands, streams, forested watersheds and other sensitive ecosystems. The MDN characterizes the extent of the mercury problem, describes regional patterns of mercury deposition, and assesses deposition changes over time. This data will be especially useful to ground truth mercury modeling efforts to predict mercury deposition as controls are added to mercury sources to reduce emissions.

Weekly wet deposition samples at the MDN mercury deposition network sites are collected using standard, clean protocols for trace metals. All MDN field technicians responsible for collecting MDN samples have received certification training at the Illinois State Water Survey (ISWS) for performance of precipitation sampling at MDN sites.

Wisconsin's participation in both the NTN and MDN networks is essential for tracking atmospheric pollution within the state and for helping to complete both the regional and national deposition picture. The Environmental Research Program plans to continue its support of these important monitoring efforts.

A visit to the National Atmospheric Deposition Program web site at http://nadp.sws.uiuc.edu/ will show network maps and data trends for both the National trends Network and the Mercury Deposition Network, along with details and photos of the monitoring sites.

ENVIRONMENTAL RESEARCH PROGRAM OUTREACH UPDATE
A number of new research project reports are due for publication in 2005-2006. Outreach efforts will focus on providing summaries of project findings and publishing them on the Focus on Energy website. The complete final research reports will also be made available on the web. We will be sending out e-mail announcements as these reports become available, so let us know if you wish to receive these updates. Send your request to ikelley@ecw.org.
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